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Kinetics and mechanism of the ruthenium(III) chloride catalyzed oxidation of butan-2-ol and methyl-1-propanol by the hexacyanoferrate(III) ion in an aqueous alkaline medium

✍ Scribed by Singh, H. S.; Singh, R. K.; Singh, S. M.; Sisodia, A. K.

Book ID
124053383
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
427 KB
Volume
81
Category
Article
ISSN
0022-3654

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of butane-2,3-diol by alkaline hexacyanoferrate (III), catalyzed by ruthenium trichloride
✍ A. Mucientes Balado; F. Santiago Jimenez; F. J. Poblete MartΓ­n; R. VarΓ³n Castell πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 143 KB πŸ‘ 2 views

with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, sinc