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Kinetics and mechanism of the osmium tetroxide-catalyzed oxidation of 2-methylpentane-2,4-diol and butane-1,4-diol with hexacyanoferrate (III) ion in aqueous alkaline medium

✍ Scribed by H.S. Singh; V.P. Singh; J.M. Singh; P.N. Srivastava


Book ID
113175677
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
416 KB
Volume
49
Category
Article
ISSN
0021-9517

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Kinetics and mechanism of the oxidation
✍ A. Mucientes Balado; F. Santiago Jimenez; F. J. Poblete MartΓ­n; R. VarΓ³n Castell πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 143 KB πŸ‘ 2 views

with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, sinc