Kinetics and mechanism of electron transfer reactions. Osmium(VIII) catalyzed oxidation of mannitol by hexacyanoferrate(III) in aqueous alkaline medium
β Scribed by Mridula Sharma; Gayatri Sharma; Beena Agrawal; C. L. Khandelwal; P. D. Sharma
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 278 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0340-4285
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The kinetics of the Os(VIII)βcatalyzed oxidation of glycine, alanine, valine, phenylalanine, isoleucine, lycine, and glutamic acid by alkaline hexacyanoferrate(III) reveal that these reactions are zero order in hexacyanoferrate(III) and first order in Os(VIII). The order in amino acid a
Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method. -The osmium(VIII) catalyzed title reaction leading to Sb(V) and Fe(CN)4-6 via formation of a catalyst-oxidant complex is utilized for the analysis of
The osmium(VII1)-catalyzed oxidation of D-proline and L(-)-methionine by alkaline hexacyanoferrate(II1) has been studied spectrophotometrically. The reactions follow kinetics different from those of the oxidation of many amino acids investigated earlier, being first order in hexacyanoferrate(II1) an