Kinetics and mechanism of oxidation of xylitol and galactitol by hexacyanoferrate(III) ion in aqueous alkaline medium
β Scribed by H. S. Singh; V. P. Singh; B. S. Arya; G. R. Varma
- Publisher
- Springer Vienna
- Year
- 1981
- Tongue
- English
- Weight
- 291 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0026-9247
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The kinetics of the Os(VIII)βcatalyzed oxidation of glycine, alanine, valine, phenylalanine, isoleucine, lycine, and glutamic acid by alkaline hexacyanoferrate(III) reveal that these reactions are zero order in hexacyanoferrate(III) and first order in Os(VIII). The order in amino acid a
The kinetics of oxidation of triethanolamine (TEA) by diperiodatoargenate(II1) anion, [Ag(HI0,)z]5-, has been studied in aqueous alkaline medium by conventional spectrophotometry. The reaction is pseudo-first-order in [Ag(III)] disappearance with kobs = (kl + &[OH-]) KlKz[TEA]/{[H210:-j+ + K1 + KIKz