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Kinetics and Mechanism of the Reactions of S -2,4-Dinitrophenyl 4-Substituted Thiobenzoates with Secondary Alicyclic Amines

✍ Scribed by Castro, Enrique A.; Aguayo, Raul; Bessolo, Jorge; Santos, José G.


Book ID
127246401
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
86 KB
Volume
70
Category
Article
ISSN
0022-3263

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Concerted mechanism of the reactions of
✍ Enrique A. Castro; Andrea Hormazabal; Jose G. Santos 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 2 views

The title reactions are subjected to a kinetic analysis in ethanol-water, at 44 wt% ionic strength 0.2 (KCl). With a large excess of amine over the substrate, pseudo-first-25.0ЊC, order rate coefficients are obtained, which are linearly dependent on the amine concen-(k ) obs tration. The nucleophili