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Concerted mechanism of the reactions of secondary alicyclic amines with O-ethyl S-(2,4,6-trinitrophenyl) thiocarbonate

✍ Scribed by Castro, Enrique A.; Salas, Mirtha; Santos, Jose G.

Book ID
126583187
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
367 KB
Volume
59
Category
Article
ISSN
0022-3263

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The reactions of the title substrate with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, 25.0Β°C, and ionic strength 0.2 M (KC1). The Bronsted-type plot (log k~ vs. pKa of the amine, where k~ is the second-order rate coefficient) obtained is linear