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Concerted mechanism of the aminolysis of O-ethyl S-(2,4-dinitrophenyl) thiocarbonate

✍ Scribed by Castro, Enrique A.; Ibanez, Fernando; Salas, Mirtha; Santos, Jose G.


Book ID
127074427
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
384 KB
Volume
56
Category
Article
ISSN
0022-3263

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The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0ЊC are studied. Relatively small values of ␀ X (␀ nuc ) Ο­ 0.6 Ο³ 0.8 and ␀ Z (␀ lg ) Ο­ Οͺ0.5 Ο³ Οͺ0.7 together with a negative cross-interaction constant XZ (Ο­ Οͺ0.47) and failure o