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Kinetics and mechanism of the aminolysis of 2,4-dinitrophenyl and 2,4,6-trinitrophenyl O-ethyl dithiocarbonates

✍ Scribed by Castro, Enrique A.; Ibanez, Fernando; Salas, Mirtha; Santos, Jose G.; Sepulveda, Patricia


Book ID
127355537
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
605 KB
Volume
58
Category
Article
ISSN
0022-3263

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Concerted mechanism of the aminolysis of
✍ Enrique A. Castro; MarΓ­a Cubillos; Gabriel MuΓ±oz; JosΓ© G. Santos πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 255 KB

The reactions of the title substrate with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, 25.0Β°C, and ionic strength 0.2 M (KC1). The Bronsted-type plot (log k~ vs. pKa of the amine, where k~ is the second-order rate coefficient) obtained is linear