𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and Mechanism of the Pyridinolysis of 2,4-Dinitrophenyl and 2,4,6-Trinitrophenyl O -Ethyl Dithiocarbonates

✍ Scribed by Castro, Enrique A.; Araneda, Carlos A.; Santos, José G.


Book ID
121843930
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
115 KB
Volume
62
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Concerted mechanism of the aminolysis of
✍ Enrique A. Castro; María Cubillos; Gabriel Muñoz; José G. Santos 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 255 KB

The reactions of the title substrate with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, 25.0°C, and ionic strength 0.2 M (KC1). The Bronsted-type plot (log k~ vs. pKa of the amine, where k~ is the second-order rate coefficient) obtained is linear