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Kinetic Study of the Phenolysis of O -Methyl and O -Phenyl O -2,4-Dinitrophenyl Thiocarbonates and O -Ethyl 2,4-Dinitrophenyl Dithiocarbonate

✍ Scribed by Castro, Enrique A.; Arellano, David; Pavez, Paulina; Santos, José G.

Book ID: 126862250
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 73 KB
Volume: 68
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo034538+

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## Abstract The reactions of the title substrates with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, at 25.0deg;C, ionic strength 0.2 M (maintained with KCl). Pseudo‐first‐order kinetics are found under amine excess. The order in amine obtained i