𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Concerted Mechanisms of the Reactions of 2,4,6-Trinitrophenyl Methyl Carbonate and 2,4,6-Trinitrophenyl Acetate with Secondary Alicyclic Amines

✍ Scribed by Castro, Enrique A.; Cubillos, María; Santos, José G.


Book ID
126583188
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
49 KB
Volume
66
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Concerted mechanism of the aminolysis of
✍ Enrique A. Castro; María Cubillos; Gabriel Muñoz; José G. Santos 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 255 KB

The reactions of the title substrate with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, 25.0°C, and ionic strength 0.2 M (KC1). The Bronsted-type plot (log k~ vs. pKa of the amine, where k~ is the second-order rate coefficient) obtained is linear

Concerted mechanism of the reactions of
✍ Enrique A. Castro; Andrea Hormazabal; Jose G. Santos 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 2 views

The title reactions are subjected to a kinetic analysis in ethanol-water, at 44 wt% ionic strength 0.2 (KCl). With a large excess of amine over the substrate, pseudo-first-25.0ЊC, order rate coefficients are obtained, which are linearly dependent on the amine concen-(k ) obs tration. The nucleophili