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Kinetics and mechanism of the reactions of 2,4-dinitrophenyl acetate with secondary alicyclic amines. Different nucleofugalities of alicyclic amines and pyridines from a tetrahedral intermediate

✍ Scribed by Castro, Enrique A.; Ureta, Carmen

Book ID: 126955543
Publisher: American Chemical Society
Year: 1990
Tongue: English
Weight: 560 KB
Volume: 55
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00292a051

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## Abstract We report a kinetic study on the reactions of secondary alicyclic amines toward 4‐nitrophenyl, 2,4‐dinitrophenyl, and 2,4,6‐trinitrophenyl acetates (**1, 2**, and **3**) in ethanol/water mixtures of different compositions. It is found that (i) the intermediate in the reaction of **1** i