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Kinetics and mechanism of the reaction of the CH2OH radical with O2molecules

✍ Scribed by L. I. Avramenko; R. V. Kolesnikova


Book ID
112434381
Publisher
Springer
Year
1961
Tongue
English
Weight
533 KB
Volume
10
Category
Article
ISSN
1573-9171

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Kinetics of the reaction of CH2OH radica
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The kinetics of the reaction of CH2OH with O(3P) has been investigated in a heatable tubular reactor coupled to a photoionization mass spectrometer. The decay of CH2OH was monitored as a function of O-atom concentration ( tO determine rate constants as a function of temperature and pressure. The ra

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The rate coefficient of the reaction CHzOH + 02 -HO2 + CH20. has been measured at 300 K by the LMR flow-tube method, and found to have the unexpectedly large value k = (2J) x 1O-'2 cm3 molecule-' s-I\_ This reaction. preceded by fiomenzafion, may be an important route for the oxidation of CHJO m the