Kinetics and mechanism of the reaction of the CH2OH radical with O2molecules
β Scribed by L. I. Avramenko; R. V. Kolesnikova
- Book ID
- 112434381
- Publisher
- Springer
- Year
- 1961
- Tongue
- English
- Weight
- 533 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The kinetics of the reaction of CH2OH with O(3P) has been investigated in a heatable tubular reactor coupled to a photoionization mass spectrometer. The decay of CH2OH was monitored as a function of O-atom concentration ( tO determine rate constants as a function of temperature and pressure. The ra
The rate coefficient of the reaction CHzOH + 02 -HO2 + CH20. has been measured at 300 K by the LMR flow-tube method, and found to have the unexpectedly large value k = (2J) x 1O-'2 cm3 molecule-' s-I\_ This reaction. preceded by fiomenzafion, may be an important route for the oxidation of CHJO m the