Kinetics and mechanism of the reaction of acetonyl radical, CH3C(O)CH2, with Br2
✍ Scribed by Zügner, Gábor L.; Szabó, Emese; Farkas, Mária; Dóbé, Sándor; Brudnik, Katarzyna; Sarzyński, Dariusz; Jodkowski, Jerzy T.
- Book ID
- 123121065
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 319 KB
- Volume
- 568-569
- Category
- Article
- ISSN
- 0009-2614
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## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0
## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m