Kinetics and mechanism of the oxidation of some α-hydroxy acids by hexamethylenetetramine-bromine
✍ Scribed by Dimple Garg; Seema Kothari
- Book ID
- 110647012
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2004
- Tongue
- English
- Weight
- 65 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0253-4134
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📜 SIMILAR VOLUMES
## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by
The oxidation of lower oxyacids of phosphorus by hexamethylenetetramine bromine (HABR) in glacial acetic acid resulted in the formation of corresponding oxyacids with phosphorus in a higher oxidation state. The reaction exhibited stoichiometry. The reaction 2 : 1 is first order with respect to HABR.