Kinetics and mechanism of the oxidation of aliphatic aldehydes by hexamethylenetetramine-bromine
β Scribed by Pareek, Arun ;Varshney, Seema ;Banerji, Kalyan K.
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 159 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The oxidation of lower oxyacids of phosphorus by hexamethylenetetramine bromine (HABR) in glacial acetic acid resulted in the formation of corresponding oxyacids with phosphorus in a higher oxidation state. The reaction exhibited stoichiometry. The reaction 2 : 1 is first order with respect to HABR.
The kinetics of the oxidation of aliphatic aldehydes, formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, and trichloroacetaldehyde by Peroxomonosulphate (PMS) was carried out in aqueous perchloric acid medium (0.1-1 M H+) a t constant ionic strength of 1.2 M in the temperature range 1O"-6
## Abstract The oxidation of six aliphatic aldehydes by tetrabutylammonium tribromide (TBATB) in aqueous acetic acid resulted in the formation of corresponding carboxylic acids. The reaction is first order with respect to TBATB and the aldehydes. The oxidation of deuteriated acetaldehyde (MeCDO) sh