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Kinetics and mechanism of the oxidation of neutralized α-hydroxy acids by tris(pyridine-2-carboxylato)manganese(III)

✍ Scribed by Kalyan K. Sen Gupta; Nandini Bhattacharjee; Biswajit Pal; Saktiprosad Ghosh

Book ID
110244993
Publisher
Springer
Year
1999
Tongue
English
Weight
139 KB
Volume
24
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of some α-hydroxy acids by 2,2′-bipyridinium chlorochromate
✍ Vinita Kumbhat; Pradeep K. Sharma; Kalyan K. Banerji 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by