The tetradentate Schiff-base ligands, N,"-bis(salicy1idene)-ethylenediamine (Salen), N,"-bis(salicy1idene) butylenediamine (Salbut), and N,N-bis(salicylidene)-o-phenylenediamine, (sal-o-phen) are very strongly sorbed by cation exchange resin (Dowex-50W) with Fez+ ions as a counter ion, forming stabl
Kinetics and mechanism of the decomposition of hydrogen peroxide catalyzed by Mn(II)-bis-salicylaldimine complexes
β Scribed by I. A. Salem; M. Y. El-Sheikh; A. B. Zaki
- Publisher
- Springer Vienna
- Year
- 1995
- Tongue
- English
- Weight
- 371 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0026-9247
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The rate of reaction of (Fe(DTPA)) with Hz02 was investigated at various temperatures. The observed rate law is given by the expression. The rate constants and the related thermodynamic parameters are calculated. Substitution controlled mechanisms are suggested to account for the formation of the v
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