The rate of reaction of (Fe(DTPA)) with Hz02 was investigated at various temperatures. The observed rate law is given by the expression. The rate constants and the related thermodynamic parameters are calculated. Substitution controlled mechanisms are suggested to account for the formation of the v
Kinetics and mechanisms of the catalyzed decomposition of hydrogen peroxide by ethylenebis(oxyethylenedinitrilo)tetracetate complex of iron(III)
β Scribed by Sami S. Anis; Wageeh G. Hanna; Shaker Labib Stefan
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 626 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0026-265X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The decomposition of alkaline hydrogen peroxide solutions at 20Β°C has been studied in the presence of both supported iron catalysts and in systems with iron initially in solution. Studies with an iron-alumina supported catalyst showed the decomposition reaction was first order with respect to total
Oscillatory change of pH occurs during the chromate-catalyzed decomposition of hydrogen peroxide in a weakly acidic medium at elevated temperature and at high initial concentration of hydrogen peroxide. In a closed system, there are only two or three periods, but sustained oscillation occurs in a CS
The hydrogen peroxide decomposition kinetics were investigated for both "free" iron catalyst [Fe(II) and Fe(III)] and complexed iron catalyst [Fe(II) and Fe(III)] complexed with DTPA, EDTA, EGTA, and NTA as ligands (L). A kinetic model for free iron catalyst was derived assuming the formation of a r