Kinetics and mechanism of hydrogen peroxide decomposition in the presence of the tetraaquapalladium(II) complex
β Scribed by V. V. Potekhin; S. N. Solov'eva; V. M. Potekhin
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 339 KB
- Volume
- 54
- Category
- Article
- ISSN
- 1573-9171
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Oscillatory change of pH occurs during the chromate-catalyzed decomposition of hydrogen peroxide in a weakly acidic medium at elevated temperature and at high initial concentration of hydrogen peroxide. In a closed system, there are only two or three periods, but sustained oscillation occurs in a CS
The rate of reaction of (Fe(DTPA)) with Hz02 was investigated at various temperatures. The observed rate law is given by the expression. The rate constants and the related thermodynamic parameters are calculated. Substitution controlled mechanisms are suggested to account for the formation of the v