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Kinetics and Mechanism of the Autocatalyzed Oxidation of Theophylline by Permanganate in Aqueous Perchloric Acid Medium

✍ Scribed by Rajeshwari V. Hosahalli, Anita P. Savanur, Sharanappa T. Nandibewoor, Shivamurti A. Chimatadar

Book ID
113072557
Publisher
Springer US
Year
2012
Tongue
English
Weight
578 KB
Volume
41
Category
Article
ISSN
0095-9782

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Kinetics and mechanism of sulfite oxidat
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✍ Teresa Ernst; Maria Cyfert; Michal Wilgocki πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 289 KB πŸ‘ 1 views

## Abstract The kinetics of the permanganate‐sulfite redox reaction has been studied in the alkaline medium using a stopped‐flow technique. In the pH range 10 to 12 the reaction was found to obey the rate expression: βˆ’Β½__d__[MnO~4~^βˆ’^]/__dt__ = (__k__~1~ + __k__~2~[OH^βˆ’^]) [MnO~4~^βˆ’^] [SO~3~^2βˆ’^].