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Kinetics and mechanism of oxidation of carbohydrazide by chloramine-T and bromamine-T in aqueous perchloric acid medium

✍ Scribed by B Thimme Gowda; P Ramachandra

Book ID
112919925
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1990
Tongue
English
Weight
385 KB
Volume
102
Category
Article
ISSN
0253-4134

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πŸ“œ SIMILAR VOLUMES

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Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine-T in aqueous solution
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## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t

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## Abstract The formation of palladium(II) complexes with aliphatic amines and their oxidation by chloramine‐T in perchloric acid medium has been studied. The spectrophotometric studies showed the formation of 1:1 and 1:2 complexes between palladium(II) and amine in absence of HClO~4~. An increase