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Kinetics and mechanism of oxidation of malonic acid by permanganate and manganese dioxide in acid perchlorate medium

✍ Scribed by Indu Rao; Som K. Mishra; Prem D. Sharma


Publisher
Springer
Year
1993
Tongue
English
Weight
428 KB
Volume
18
Category
Article
ISSN
0340-4285

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## Abstract The kinetics of the permanganate‐sulfite redox reaction has been studied in the alkaline medium using a stopped‐flow technique. In the pH range 10 to 12 the reaction was found to obey the rate expression: βˆ’Β½__d__[MnO~4~^βˆ’^]/__dt__ = (__k__~1~ + __k__~2~[OH^βˆ’^]) [MnO~4~^βˆ’^] [SO~3~^2βˆ’^].