𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of the permanganate oxidation of acetylenedicarboxylic acid

✍ Scribed by L.I. Simándi; M. Jáky


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
186 KB
Volume
11
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Mechanism and kinetics of hypophosphite
✍ K. Wojciechowski; A. Malecki 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 154 KB 👁 2 views

The kinetics of the permanganate-hypophosphite redox reaction has been studied over a wide range of pH by using a stopped-flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The prop

Effect of Micelles on kinetics and mecha
✍ M. Yousuf Hussain; Firoz Ahmad 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 685 KB

The oxidation of serine (HORC0,H) by acid permanganate was investigated both in the absence and presence of sodium dodecyl sulfate (SDS). It has been observed that the presence of surfactant enhanced the reaction rate. The reaction is first order with respect to [Serine] and [MnO,-1. The reaction is

Kinetics and mechanism of the oxidation
✍ Miklós Jáky; János Szammer; Edit Simon-Trompler 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

## Abstract The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in

Kinetics and mechanism of the oxidation
✍ Sridevi Nadimpalli; Rambabu Rallabandi; L. S. A. Dikshitulu 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 444 KB

The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa