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Kinetics and mechanism of oxidations by peroxydiphosphate ions—V Oxidation of iodide in aqueous perchloric acid

✍ Scribed by Lalit Mohan Bharadwaj; Devendra Nath Sharma; Yugul Kishore Gupta

Book ID
115974622
Publisher
Elsevier Science
Year
1977
Weight
164 KB
Volume
39
Category
Article
ISSN
0022-1902

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✍ T. Peter Amala Dhas; D. K. Mishra; R. K. Mittal; Y. K. Gupta 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 566 KB

The reaction of peroxomonophosphoric acid and hydrazinium ion in acid perchlorate solutions occurs as per stoichiometry (i), and the rate law (ii) at large [NzH~'], (i) where K& is the first acid dissociation constant of H3P05 and kl and kz are rate constants found to be 2.6 x s-' and 5.0 x lo-' M