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Kinetics and mechanism of oxidations by peroxodiphosphate—IV: Stoichiometry and kinetics of oxidations of antimony(III), hydrazine and nitrite in aqueous perchloric acid medium

✍ Scribed by Surinder Kapoor; Y.K. Gupta

Book ID
115974761
Publisher
Elsevier Science
Year
1977
Weight
224 KB
Volume
39
Category
Article
ISSN
0022-1902

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Kinetics and mechanism of oxidation of antimony(III) by keggin-type 12-tungstocobaltate(III) in aqueous hydrochloric acid medium
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## Abstract The reaction between Sb(III) and [Co^III^W~12~O~40~]^5−^ proceeds with two, one‐electron steps; formation of unstable Sb(IV) is the slow first step followed by its reaction with another oxidant in a fast step. The reaction rate is unaffected by the [H^+^] as there are no protonation equ