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Kinetics and Mechanism of Oxidation ofL-Leucine by Alkaline Diperiodatonickelate(IV) – A Free Radical Intervention, Deamination, and Decarboxylation

✍ Scribed by R. T. Mahesh; Pandurang D. Pol; Sharanappa T. Nandibewoor


Publisher
Springer Vienna
Year
2003
Tongue
English
Weight
304 KB
Volume
134
Category
Article
ISSN
0026-9247

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The kinetics of Ru(III) catalysed oxidation of neuroleptic drug, gabapentin by diperiodatonickelate(IV) (DPN) in alkaline medium at 298 K and a constant ionic strength of 0.30 mol dm -3 was studied spectrophotometrically. The oxidation products are 1-(hydroxymethyl) cyclohexane acetic acid and Ni(II