Kinetics of oxidation of cinnamaldehyde (Cinn) by chloramine-T (CAT) has been studied in solutions containing HCl and H2S04 at 313 K. The respective experimental rate laws obtained in HCl and HZS04 media are as follows: (1) and Here the value of x varies from 0.9 to zero while the values of y and
Kinetics and mechanism of oxidation of leucine by chloramine-T in alkaline media
β Scribed by Adarsh Kumar; A. K. Bose; Sukhdeo P. Mushran
- Publisher
- Springer Vienna
- Year
- 1975
- Tongue
- English
- Weight
- 241 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0026-9247
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π SIMILAR VOLUMES
The kinetics of oxidation of aliphatic amines viz., ethylamine, n-butylamine, isopropylamine (primary amines), diethylamine (secondary amine), and triethylamine (tertiary amine) by chloramine-T have been studied in NaOH medium catalyzed by osmium(W1) and in perchloric acid medium with ruthenium(II1)
## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramineβT (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is β__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t
Kinetics of oxidation of thiosemicarbazide (TSC) and its hydrazone (Benzaldehyde thiosemicarbazone) by chloramine-T (CAT) and dichloramine-T (DCT) in aqueous methanol medium in the presence of perchloric acid has been studied. Oxidation of TSC by both the oxidants showed first order dependences in [