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Kinetics and mechanism of osmium(VIII)-catalysed and uncatalysed oxidation of aminoalcohols by chloramine-T in alkaline medium

โœ Scribed by Sushma Gupta; Vazid Ali; Santosh K. Upadhyay

Publisher
Springer
Year
1988
Tongue
English
Weight
457 KB
Volume
13
Category
Article
ISSN
0340-4285

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๐Ÿ“œ SIMILAR VOLUMES

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The kinetics of oxidation of aliphatic amines viz., ethylamine, n-butylamine, isopropylamine (primary amines), diethylamine (secondary amine), and triethylamine (tertiary amine) by chloramine-T have been studied in NaOH medium catalyzed by osmium(W1) and in perchloric acid medium with ruthenium(II1)

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The kinetics and mechanism of Os(VIl1) utalysed oxidation of some suhstituted transcinnnmic acids by chlonmine-T in presence of alkaline medium has been investigated. The order with respect to [CAT] is zero and is lOsO ] one. The reaction is fractional order in [substrate]. The rate dependace on [OH