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Oxidations by iron(VI). Kinetic study of uncatalysed and osmium(VIII) catalysed oxidation of dimethyl sulphoxide in alkaline medium

โœ Scribed by K. Laxmi Venkat Rao; M. Prasada Rao; B. Sethuram; T. Navaneeth Rao


Publisher
Springer
Year
1989
Tongue
English
Weight
421 KB
Volume
14
Category
Article
ISSN
0340-4285

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โœ S. Ananda; T. Demappa; N. M. Made Gowda ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 166 KB ๐Ÿ‘ 2 views

The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะŠC. In the presence of the catalyst, the experimental rate law