Kinetics and mechanisms of oxidation by metal ions. Part XIII. Osmium(VIII)-catalysed oxidation of cycloalkanols by alkaline hexacyanoferrate(III)
โ Scribed by Satya Pal S. Mehta; Raj N. Mehrotra
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 520 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0340-4285
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The stopped-flow measurements on the disappearance of alkaline osmium(VII1) at 402 nm indicated a first-order dependence each in [Os(VIII)] and [HCHO]. The pseudo first-order rate constant hobs ([HCHO] & [Os(VIII)]) decreased with increasing [OH-]. The ionic strength, however, had no effect on kobs.
Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method. -The osmium(VIII) catalyzed title reaction leading to Sb(V) and Fe(CN)4-6 via formation of a catalyst-oxidant complex is utilized for the analysis of
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