A kinetic and mechanistic study on oxidation of Isoniazid drug by alkaline diperiodatocuprate(III) – A free radical intervention
✍ Scribed by Suresh D. Kulkarni; Sharanappa T. Nandibewoor
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 239 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The kinetics of oxidation of vanillin (VAN) by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of 0.50 mol dm^−3^ was studied spectrophotometrically. The reaction between DPC and vanillin in alkaline medium exhibits 1:2 stoichiometry (vanillin: DPC). The re
The kinetics of oxidation of Isoniazid (INH) by sodium N-haloarenesulfonamidates, chloramine-T (CAT), bromamine-T (BAT), chloramine-B (CAB), and bromamine-B (BAB), has been studied in alkaline medium at 303 K. The oxidation reaction follows identical kinetics with a first-order dependence on each [o