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Kinetics and mechanism of ethylene homopolymerization and copolymerization reactions with heterogeneous Ti-based Ziegler–Natta catalysts

✍ Scribed by Yury V. Kissin; Robert I. Mink; Thomas E. Nowlin; Anita J. Brandolini

Book ID
110386490
Publisher
Springer
Year
1999
Tongue
English
Weight
392 KB
Volume
7
Category
Article
ISSN
1022-5528

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📜 SIMILAR VOLUMES

Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. I. Ethylene polymerization kinetics and kinetic mechanism
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 287 KB 👁 1 views

Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r

Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. III. Chain-end structures and polymerization mechanism
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin; A. J. Brandolini 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 306 KB 👁 2 views

Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit a number of features that differentiate them from polymerization reactions of ␣ olefins: (1) a relatively low ethylene reactivity, (2) markedly higher polymerization rates in the presence of ␣ olefins, (3) a high reaction or