Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r
Peculiarities of Ethylene Polymerization Reactions with Heterogeneous Ziegler–Natta Catalysts: Kinetic Analysis
✍ Scribed by Yury V. Kissin
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 171 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1022-1344
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Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of ␣-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of ␣-olefins, a high reaction order with respect to ethy
Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit a number of features that differentiate them from polymerization reactions of ␣ olefins: (1) a relatively low ethylene reactivity, (2) markedly higher polymerization rates in the presence of ␣ olefins, (3) a high reaction or
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