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On the reaction mechanism of the ethylene polymerization with heterogeneous ziegler-natta catalysts

✍ Scribed by P. Cossee


Publisher
Elsevier Science
Year
1960
Tongue
French
Weight
236 KB
Volume
1
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Ethylene polymerization reactions with Z
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 287 KB πŸ‘ 1 views

Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r

Ethylene polymerization reactions with Z
✍ Y. V. Kissin; A. J. Brandolini πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 151 KB πŸ‘ 1 views

Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of ␣-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of ␣-olefins, a high reaction order with respect to ethy

Ethylene polymerization reactions with Z
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin; A. J. Brandolini πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 306 KB πŸ‘ 2 views

Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit a number of features that differentiate them from polymerization reactions of ␣ olefins: (1) a relatively low ethylene reactivity, (2) markedly higher polymerization rates in the presence of ␣ olefins, (3) a high reaction or

Ethylene polymerization with homogeneous
✍ Roberto Fusco; Luca Longo; Francesco Masi; Fabio Garbassi πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 420 KB πŸ‘ 1 views

## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = Ξ·~5~‐C~5~H~5~), as a model for olefin polymerization with homogeneous Ziegler‐Natta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c

The polymerization of ethylene with a hi
✍ A.E. Yildirim πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 345 KB

A soluble ethylene catalyst were obtained by mixing a methylene dichloride solution of dichlorobislT-cyclopentadienyl) titanium (Cp2TiCI2) with a heptane solution of ethylaluminium sesquichloride (AlzEt3C13) or of diethylaluminium chloride {AIEt2CI). Ethylene was polymerized using these catalysts; t