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Kinetic Comparison of Ethylene and Propylene Polymerization Reactions with Ziegler—Natta Catalysts

✍ Scribed by Yury V. Kissin


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Ethylene polymerization reactions with Z
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Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r

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Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit a number of features that differentiate them from polymerization reactions of ␣ olefins: (1) a relatively low ethylene reactivity, (2) markedly higher polymerization rates in the presence of ␣ olefins, (3) a high reaction or

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