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Kinetics and Equilibrium Constants for Reactions of α-Phenyl-Substituted Cyclopropylcarbinyl Radicals

✍ Scribed by Halgren, Thomas A.; Roberts, John D.; Horner, John H.; Martinez, Felix N.; Tronche, Christopher; Newcomb, Martin


Book ID
127240271
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
130 KB
Volume
122
Category
Article
ISSN
0002-7863

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✍ Tomohiro Ohta 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 417 KB 👁 2 views

Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o