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A convenient method for kinetic studies of fast radical rearrangements. Rate constants and Arrhenius function for the cyclopropylcarbinyl radical ring opening

✍ Scribed by Newcomb, Martin; Glenn, Anne G.


Book ID
127358496
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
398 KB
Volume
111
Category
Article
ISSN
0002-7863

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## Abstract Intrinsic spectral and kinetic parameters have been measured for the ethyl radical, which was formed in the gas phase by the flash photolysis of azoethane. Absolute values of the extinction coefficient Ο΅(Ξ») were derived from complementary measurements of the yield of nitrogen and the ab