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Kinetics and atmospheric implications of the gas-phase reactions of nitrate radicals with a series of monoterpenes and related organics at 294 .+-. 2 K

✍ Scribed by Atkinson, Roger.; Aschmann, Sara M.; Winer, Arthur M.; Pitts, James N.

Book ID: 127335424
Publisher: American Chemical Society
Year: 1985
Tongue: English
Weight: 591 KB
Volume: 19
Category: Article
ISSN: 0013-936X
DOI: 10.1021/es00132a009

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Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with a series of monoterpenes have been determined in one atmosphere of air at 294 5 1 K. Relative to a rate constant for the reaction of OH radicals with 2,3-dimethyl-2-butene of 1.12 lo-'' cm3 molecule-'

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Using a relative rate technique, rate constants have been determined for the gas phase reactions of C1 atoms with a series of organics at 296 5 2 K and atmospheric pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-' for the reaction of C1 atoms with n-butane, the following rate

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## Abstract Relative rate constants for the gas‐phase reactions of OH radicals with a series of alkyl nitrates have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−1

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