Kinetics of the gas-phase reactions of nitrate radicals with a series of dialkenes, cycloalkenes, and monoterpenes at 295 .+-. 1 K
โ Scribed by Atkinson, Roger.; Aschmann, Sara M.; Winer, Arthur M.; Pitts, James N.
- Book ID
- 111917267
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 786 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0013-936X
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๐ SIMILAR VOLUMES
Using a relative rate technique, rate constants for the gas phase reactions of the OH radical with n-butane, n-hexane, and a series of alkenes and dialkenes, relative to that for propene, have been determined in one atmosphere of air at 295 f 1 K. The rate constant ratios obtained were (propene = 1.
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with a series of monoterpenes have been determined in one atmosphere of air at 294 5 1 K. Relative to a rate constant for the reaction of OH radicals with 2,3-dimethyl-2-butene of 1.12 lo-'' cm3 molecule-'
Rate constants for the gas phase reactions of 0, and OH radicals with 1,3-cycloheptadiene, 1,3,5-cycloheptatriene, and cis-and trans-1,3,5-hexatriene and also of 0, with cis-2,trans-4-hexadiene and trans-2frans-4-hexadiene have been determined at 294 ? 2 K. The rate constants determined for reaction
## Abstract Relative rate constants for the gasโphase reactions of OH radicals with a series of alkyl nitrates have been determined at 299 ยฑ 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 ร 10^โ1