## Abstract The relativeโrate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2โmethylโ3โbutenโ2โol (__k__~1~), 3โmethylโ3โbutenโ1โol (__k__~2~), and 3โmethylโ2โbutenโ1โol (__k__~3~), in the gas phase. OH radicals were prod
Rate constants for the gas-phase reactions of nitrate radicals with a series of organics in air at 298 .+-. 1 K
โ Scribed by Atkinson, Roger; Plum, Christopher N.; Carter, William P. L.; Winer, Arthur M.; Pitts, James N.
- Book ID
- 126298232
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 725 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
## Abstract Rate constants for the gasโphase reactions of O~3~ with ethene, propene, 1โhexene, 1โheptene, styrene, __o__โ, __m__โ, and __p__โcresol, __o__โ and __m__โxylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ยฑ 2 K. The rate constants ranged from <5 ร 10^
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with a series of monoterpenes have been determined in one atmosphere of air at 294 5 1 K. Relative to a rate constant for the reaction of OH radicals with 2,3-dimethyl-2-butene of 1.12 lo-'' cm3 molecule-'
Rate coefficients for the reactions of difunctional nitrates with atmospherically important OH radicals are not currently available in the literature. This study represents the first determination of rate coefficients for a number of C(3) and C(4) carbonyl nitrates and dinitrates with OH radicals in
Rate constants for the reactions of OH radicals with CH2-CHN02, CH2-CH-CH,NOZ and c-CaHsNOz have been determined at 298?2 K and a total pressure of 1 atm. Rate data for the reaction of OH radicals with CH2-CHZ, CH2=CH-CH3 and C-C&~ were also obtained for comparison purposes. The OH rate data for all
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