Using a relative rate technique, rate constants have been determined for the gas-phase reactions of C1 atoms with the cholorethenes and ethane at 298 t 2 K and 735 torr total pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-l for the reaction of C1 atoms with n-butane, the fol
Kinetics of the gas phase reaction of Cl atoms with a series of organics at 296 ± 2 K and atmospheric pressure
✍ Scribed by Roger Atkinson; Sara M. Aschmann
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 403 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Using a relative rate technique, rate constants have been determined for the gas phase reactions of C1 atoms with a series of organics at 296 5 2 K and atmospheric pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-' for the reaction of C1 atoms with n-butane, the following rate constants (in units of lo-'' cm3 molecule-' s -' ) were obtained:
📜 SIMILAR VOLUMES
The relative rate technique has been used to determine the rate constants for the reaction of chlorine atoms with a series of oxygenated organic species. Experiments were performed a t 295 t 2 K and atmospheric pressure of synthetic air or nitrogen. The decay rates of the organic species were measur
Relative rate techniques were used to measure k(Cl This result is discussed with respect to the available data.
## Abstract Using a relative rate method, rate constants for the gas phase reactions of O~3~ with 1‐ and 3‐methylcyclopentene, 1‐, 3‐, and 4‐methylcyclohexene, 1‐methylcycloheptene, __cis__‐cyclooctene, 1‐ and 3‐methylcyclooctene, 1,3‐ and 1,5‐cyclooctadiene, and 1,3,5,7‐cyclooctatetraene have been
## Abstract Rate constants for the gas‐phase reactions of O~3~ with ethene, propene, 1‐hexene, 1‐heptene, styrene, __o__‐, __m__‐, and __p__‐cresol, __o__‐ and __m__‐xylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ± 2 K. The rate constants ranged from <5 × 10^
## Abstract Rate constants for the gas‐phase reactions of O~3~ with the carbonyls acrolein, crotonaldehyde, methacrolein, methylvinylketone, 3‐penten‐2‐one, 2‐cyclohexen‐1‐one, acetaldehyde, and methylglyoxal have been determined at 296 ± 2 K. The rate constants ranged from <6 × 10^−21^ cm^3^ molec