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Kinetic study of the reactions of O-alkylisoureas with OH-acidic compounds

✍ Scribed by Rolf Jaeger

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 136 KB
Volume: 11
Category: Article
ISSN: 0894-3230
DOI: 10.1002/(sici)1099-1395(199801)11:1<47::aid-poc965>3.0.co;2-y

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✦ Synopsis

Kinetic investigations on the reaction of N,N'-dicyclohexyl-O-(1-methylheptyl)isourea with acetic acid are described. The conversion proceeds partly through the intermediacy of a methylheptylcarbenium ion. However, in dilute solution an S N 2 mechanism prevails. The results are discussed in terms of the simultaneous existence of two discrete mechanisms.

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