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Kinetic Study of the Reaction CHI 3 + HI ⇄ CH 2 I 2 + I 2 . A Summary of Thermochemical Properties of Halomethanes and Halomethyl Radicals

✍ Scribed by Furuyama, Shoza; Golden, David M.; Benson, Sidney W.

Book ID
126082545
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
637 KB
Volume
91
Category
Article
ISSN
0002-7863

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Kinetic studies of the reactions CH2I2 +
Kinetic studies of the reactions CH2I2 + HI⇄CH3I + I2 and 2 CH3I⇄CH4 + CH2I2 the heat of formation of the iodomethyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB 👁 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k