A theoretical study of H- and I-abstraction reactions from CH3I molecule by I (2P3/2) atom and IO radical
✍ Scribed by Cours, Thibaud; Canneaux, Sébastien; Hammaecher, Catherine; Ribaucour, Marc
- Book ID
- 121404385
- Publisher
- Elsevier
- Year
- 2013
- Tongue
- English
- Weight
- 877 KB
- Volume
- 1012
- Category
- Article
- ISSN
- 2210-271X
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📜 SIMILAR VOLUMES
The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k
The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-pm emission from I\*('PLI2) has been used to measure the rate constants for deactivation of I\* by CH31, C'HJ, CF31, and CH,. The recommended values are (2.76 2 0.22) x (2.