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A theoretical study of H- and I-abstraction reactions from CH3I molecule by I (2P3/2) atom and IO radical

✍ Scribed by Cours, Thibaud; Canneaux, Sébastien; Hammaecher, Catherine; Ribaucour, Marc


Book ID
121404385
Publisher
Elsevier
Year
2013
Tongue
English
Weight
877 KB
Volume
1012
Category
Article
ISSN
2210-271X

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Kinetic studies of the reactions CH2I2 +
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB 👁 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k

Deactivation of I(52P1/2) by CF3I, CH3I,
✍ Z-N. Gu; A. T. Young; P. L. Houston 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 394 KB

The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-pm emission from I\*('PLI2) has been used to measure the rate constants for deactivation of I\* by CH31, C'HJ, CF31, and CH,. The recommended values are (2.76 2 0.22) x (2.