Reaction of O(3P) with the alkyl iodides: CF3I, CH3I, CH2I2, C2H5I, 1-C3H7I and 2-C3H7I
โ Scribed by Teruel, M. A.; Dillon, T. J.; Horowitz, A.; Crowley, J. N.
- Book ID
- 121481516
- Publisher
- Royal Society of Chemistry
- Year
- 2004
- Tongue
- English
- Weight
- 180 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/B316402K
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๐ SIMILAR VOLUMES
The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-pm emission from I\*('PLI2) has been used to measure the rate constants for deactivation of I\* by CH31, C'HJ, CF31, and CH,. The recommended values are (2.76 2 0.22) x (2.
UV absorption spectra of i-&H, and i-C,H70Z radicals have been obtained following pulse radiolysis of Hz/&H6 and H&HdOr mixtures at a total pressure of 1 atm at room temperature. The i-C3H7 spectrum shows two absorption maxima with t( 233 nm) =89Of. 130 M-' cm-' and ~(205 nm) =780+ 120 M-' cm-', res