✦ LIBER ✦

Kinetic study of the reaction between CN AND O2 from 295 to 710 K

✍ Scribed by J.L. Durant Jr.; Frank P. Tully

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 439 KB
Volume: 154
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87154-4

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✦ Synopsis

We have extended the highly precise laser photolysis/cw laser-induced fluorescence technique to the study of CN-radical reaction kinetics. We investigated the reaction of CN with O2 over the temperature range 295-7 IO K. The measured reaction-rate coeflicients are well represented over this temperature range by the two-parameter Arrhenius expression, k= ( 1.24 20.04) x IO-" exp[ (1630 4 100) J mol-'/RT] cm' molecule-' SC', where the quoted uncertainties represent * Zoestimates of the total experimental error. NC0 forms as a direct product of the reaction.

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