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An HT FFR kinetics study of the reaction between AlCl and CO2 from 1175 to 1775 K

โœ Scribed by Donald F. Rogowski; Arthur Fontijn

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
351 KB
Volume
132
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Rate coefficients for the reaction AlCl + CO2 -+ OAlCl + CO have been measured in a huh-temperat~e fast-flow reaetor (HT FFR). These fit the expression k(T) = 2.5 X lo-l2 exp(-7550 K/T) cm3 moleculeW1 s-l. The existence of a large energy barrier for this exothermic reaction is in agreement with that suggested for the OAlCl channel of the AU+ 02 reaction. The presence of such barriers is in sharp contrast to the A10 reactions with CO2 and 02.

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