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An HTFFR kinetics study of the reaction between BCl and O2 from 540 to 1670 K

✍ Scribed by Aleksandar G. Slavejkov; Donald F. Rogowski; Arthur Fontijn

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 302 KB
Volume: 143
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87005-2

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✦ Synopsis

A method for the production of BCl in flow systems has been developed and used for the study of the title reaction in a hi& temperature fast-flow reactor (HTFFR). The temperature dependence of the rate coefficients is described by the expression k(T) =2.2x lo-"exp( -4620 K/T) cm' molecule-' s-', consistent with asingle reaction mechanism for the given temperature range. These k( T) values are larger than those observed for the isoelectronic AlCl+ O2 and BF t O2 reactions.

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