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Kinetic resolution of racemic α-hydroxy ketones by lipase-catalyzed irreversible transesterification

✍ Scribed by Waldemar Adam; María Teresa Díaz; Rainer T. Fell; Chantu R. Saha-Möller

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
229 KB
Volume
7
Category
Article
ISSN
0957-4166

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Resolution of racemic carboxylic acids via the lipase-catalyzed irreversible transesterification of vinyl esters
✍ Toshifumi Miyazawa; Sota Kurita; Masanori Shimaoka; Shinichi Ueji; Takashi Yamad 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The lipase-catalyzed irreversible transesterification procedure using vinyl esters was applied to the resolution of racemic 2-phenoxypropanoic acids. Aspergillus niger lipase showed high enantioselectivities and reasonable reaction rates. The enantioselectivity was found to be affected profoundly by